Reese Witherspoon & Ryan Phillippe, Cruel Intentions
The couple in this film would go on to actually get married outside of their screentime, which only added to their chemistry. Though they have since divorced, if you ever miss the good old days of a classic 1990's couple, just put this film on your TV and relax. Things get hot and steamy for everyone involved, which makes this a classic must-watch.
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